It is hard to find much info out about these valves.
JACMusic has this to say. But it is about the Telefunken.
Year: Appr 1940...1950.
This is NOS VALVO branded AD1, but inside I see the characteristic (getter pill) TELEFUNKEN system. These are the one and only best ever AD1. In a nice VALVO box, but not belonging to this tube originally. Sorry for the price, but try to find REAL AD1 NOS and a perfect curves plot along with it.
The tube has an original label on it: 'GEGENTAKT' which means it is possible to use it also for a push pull amplifier. This was a selection for higher peak emission. So this tube is the finest of all AD1 you can ever get. It confirms from the tube curves, they are magnificent. I bought tube from a collector who is getting too old, and selling off his stuff. I know definitely he never used it, only test it as on a Funke W19 before selling to me.
Valvo bought the early AD1 (barium pill) from Telefunken. The later, Barium coated versions, is the Siemens EbIII rebranded or the Tungsram /Philips rebranded. The Tungsram /Philips have a reputation to develop grid current or gas if you buy NOS. However, the TFK barium pill tubes are finest quality. As far as I experienced myself, any NOS comes out of the box with exact specifications, as if put in yesterday. They do not even need a burn in. It needs no explanation why tube collectors prefer the NOS Barium pill TFK tubes. You recognize those by a bubble on the middle of the plate, inside which was the Barium pill before closure of the bulb. By the activation process, they managed to have that evaporated and have it condensed on the filament. I think with an electrostatic field. At that time already a 'secret' process, and today the real secrets of the process has been lost as most old engineers have passed away now."