Hey Myles:
There is no technical reason why a digital recording would sound better pressed to vinyl.
That, in my opinion, is in the eye of the beholder. It is one generation further removed from the master.
It is an interesting topic!
Actually is it when you think about the manufacturing of a CD, esp. a while ago when serious jitter issues were happening at the production facilities. Why would the same digital master sent to two different manufacturing facilities (US and Canada) sound different as in the Holly Cole release?