I didn't quite follow that, Tony. It is very true that bi- (or whatever-) amping, i.e. directly driving the individual speakers from an amp, using a crossover before the amplifiers, will almost always work better than using a crossover. The difference may be quite small, or not (I have seen it be a big difference or almost none, measured and heard). Either way, and IMO, the speaker, not the amp, is still the major source of distortion in the system.
Whether the amp's output is better or not depends upon the speaker... In some cases, the crossover network provides a better impedance match and makes the speaker easier for the amplifier to drive. Not always true, not by a long shot, but worth mentioning.
Note that a lot of crossover mods don't only change component "quality" but also tweak the actual crossover points. The latter may have a much larger impact on the sound, for better or worse. In terms of components, I have not done a lot of crossover mods, but my experience has been than better inductors provide the most bang for the buck by going to larger wire (better effective damping factor, lower loss, higher Q). Changing capacitors never seemed to do as much for me. In this case, your mileage may definitely vary. - Don