Cleaning agents work differently for different soils.
Lets differentiate the easiest - particles:
-Per the book, "XII.6.a ...there is an entire science on the removal of particles from surfaces....The paper Adhesion and Removal of Fine Particles on Surfaces, Aerosol Science and Technology, M. B. Ranade, 1987 (38) shows for aluminum oxide particles, the force (acceleration) required to remove a 10-micron particle is 4.5 x 10^4 g’s, a 1-micron particle is 4.5 x 10^6 g’s and a 0.1-micron particle is 4.5 x 10^8 g’s." You are not going to develop the force to remove these particles w/o agitation.
-And,. as fluid flows past a surface, a boundary layer is developed and depending on its thickness (upwards of 5 microns) it will essentially shield any particles within it. So, agitation (and the associated fluid shear force) is critical in reducing the boundary layer to expose the surface within it as is back-&-forth motion (see the book XIII.3)
Organic types soils such as oil, grease, and variations thereof can be removed with the following, but each requires a different process:
-Solvents such as alcohol and enzymes - these need time to soak to either be absorbed by the soil (solvent swell), to dissolve it (solvent & enzyme) or to break-it up (enzyme). But enzymes and solvent are soil specific. In enzymes there is the Lock & Key analogy. The enyzme Key must fit the soil-Lock or nothing will happen. However, once soaked, they still need agitation to remove what swelled or what broke-up but was not dissolved.
-Surfactants work by surrounding, lifting and breaking-up soils. They need agitation. BUT, most enzyme cleaners have surfactants to assist with wetting, surrounding and lifting soils that were only broken-up.
The days of the universal solvent that could dissolve just about anything are gone. Per the book Forward,
Wishful Thinking: Everyone wants the silver bullet – the single cleaning solution. There was only one safe, nonflammable, cheap, superior solvent ever manufactured that could degrease and remove fine particulate in one step with a boiling point low enough to dry quickly leaving essentially no residue, and compatible with just about all materials - 1,1,2-Trichloro-1,2,2-trifluoroethane (CFC-113), often known as Freon® PCA (precision cleaning agent). Unfortunately, chloro-fluorocarbon CFC-113 had this “small” problem with damaging the ozone layer, and by the Montreal Protocol of 1986, all manufacture stopped 1996. In its place were created the many equivalent aqueous cleaning processes now in-use. As a note of caution, non-flammable, high performance chlorinated hydrocarbon solvents such as perchloroethylene that are still manufactured; and easily purchased, are not CFCs but are highly toxic and known to cause cancer among other unpleasant effects.